Experimental chemistry / James F. Hall.
By: Hall, James F.
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Item type | Current library | Call number | Copy number | Status | Date due | Barcode | Item holds |
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Introduction -- Experiments: Glassworking -- Laboratory techniques and measuring instruments -- The measurement of temperature -- Density determinations -- Identification of a substance -- Resolution of mixtures I: filtration and distillation -- Resolution of mixtures II: chromatography -- The solubility of a salt -- Stoichiometric determinations -- Hydrates -- Preparation and properties of some common gases -- The gas laws -- Molecular weight of a volatile liquid -- Vapor pressure -- Calorimetry -- Atomic spectroscopy -- Properties of some representative elements -- Molecular structures and shapes -- Classes of chemical reactions -- Gravimetric analysis -- Water and water pollutants -- Colligative properties of solutions -- Colloids -- Rates of chemical reactions -- Chemical equilibrium -- Acids, bases and buffer systems -- Acid/base titrations -- Determination of iron by redox titration -- The solubility product of silver acetate -- Electrochemistry I: chemical cells -- Electrochemistry II: Electrolysis -- Coordination compounds -- Qualitative analysis of organic compounds -- Organic chemical compounds -- The preparation and properties of esters -- Polymeric substances -- Inorganic preparations -- Qualitative analysis: techniques -- Qualitative analysis of the group I cations -- Qualitative analysis of the group II cations -- Qualitative analysis of the group III cations -- Qualitative analysis of the group IV and V cations -- Qualitative analysis of selected anions -- Identification of an unknown salt.
Table of contents provided by Syndetics
- Note: Each chapter concludes with a Summary, Key Terms, and Questions and Exercises
- 1 Chemical Foundations
- 1.1 Chemistry: An Overview
- 1.2 The Scientific Method
- 1.3 Units of Measurement
- 1.4 Uncertainty in Measurement
- 1.5 Significant Figures and Calculations
- 1.6 Dimensional Analysis
- 1.7 Temperature
- 1.8 Density
- 1.9 Classification of Matter
- 2 Atoms, Molecules, and Ions
- 2.1 The Early History of Chemistry
- 2.2 Fundamental Chemical Laws
- 2.3 Dalton's Atomic Theory
- 2.4 Early Experiments to Characterize the Atom
- 2.5 The Modern View of Atomic Structure: An Introduction
- 2.6 Molecules and Ions
- 2.7 An Introduction to the Periodic Table
- 2.8 Naming Simple Compounds
- 3 Stoichiometry
- 3.1 Atomic Masses
- 3.2 The Mole
- 3.3 Molar Mass
- 3.4 Percent Composition of Compounds
- 3.5 Determining the Formula of a Compound
- 3.6 Chemical Equations
- 3.7 Balancing Chemical Equations
- 3.8 Stoichiometric Calculations: Amounts of Reactants and Products
- 3.9 Calculations Involving a Limiting Reactant
- 4 Types of Chemical Reactions and Solution Stoichiometry
- 4.1 Water, the Common Solvent
- 4.2 The Nature of Aqueous Solutions: Strong and Weak Electrolytes
- 4.3 The Composition of Solutions
- 4.4 Types of Chemical Reactions
- 4.5 Precipitation Reactions
- 4.6 Describing Reactions in Solution
- 4.7 Stoichiometry of Precipitation Reactions
- 4.8 Acid-Base Reactions
- 4.9 Oxidation-Reduction Reactions
- 4.10 Balancing Oxidation-Reduction Equations
- 5 Gases
- 5.1 Pressure
- 5.2 The Gas Laws of Boyle, Charles, and Avogadro
- 5.3 The Ideal Gas Law
- 5.4 Gas Stoichiometry
- 5.5 Dalton's Law of Partial Pressures
- 5.6 The Kinetic Molecular Theory of Gases
- 5.7 Effusion and Diffusion
- 5.8 Real Gases
- 5.9 Chemistry in the Atmosphere
- 6 Thermochemistry
- 6.1 The Nature of Energy
- 6.2 Enthalpy and Calorimetry
- 6.3 Hess's Law
- 6.4 Standard Enthalpies of Formation
- 6.5 Present Sources of Energy
- 6.6 New Energy Sources
- 7 Atomic Structure and Periodicity
- 7.1 Electromagnetic Radiation
- 7.2 The Nature of Matter
- 7.3 The Atomic Spectrum of Hydrogen
- 7.4 The Bohr Model
- 7.5 The Quantum Mechanical Model of the Atom
- 7.6 Quantum Numbers
- 7.7 Orbital Shapes and Energies
- 7.8 Electron Spin and the Pauli Principle
- 7.9 Polyelectronic Atoms
- 7.10 The History of the Periodic Table
- 7.11 The Aufbau Principles and the Periodic Table
- 7.12 Periodic Trends in Atomic Properties
- 7.13 The Properties of a Group: The Alkali Metals
- 8 Bonding: General Concepts
- 8.1 Types of Chemical Bonds
- 8.2 Electronegativity
- 8.3 Bond Polarity and Dipole Moments
- 8.4 Ions: Electron Configurations and Sizes
- 8.5 Formation of Binary Ionic Compounds
- 8.6 Partial Ionic Character of Covalent Bonds
- 8.7 The Covalent Chemical Bond: A Model
- 8.8 Covalent Bond Energies and Chemical Reactions
- 8.9 The Localized Electron Bonding Model
- 8.10 Lewis Structures
- 8.11 Exceptions to the Octet Rule
- 8.12 Resonance
- 8.13 Molecular Structure: The VSEPR Model
- 9 Covalent Bonding: Orbitals
- 9.1 Hybridization and the Localized Electron Model
- 9.2 The Molecular Orbital Model
- 9.3 Bonding in Homonuclear Diatomic Molecules
- 9.4 Bonding in Heteronuclear Diatomic Molecules
- 9.5 Combining the Localized Electron and Molecular Orbital Models
- 10 Liquids and Solids
- 10.1 Intermolecular Forces
- 10.2 The Liquid State
- 10.3 An Introduction to Structures and Types of Solids
- 10.4 Structure and Bonding in Metals
- 10.5 Carbon and Silicon: Network Atomic Solids
- 10.6 Molecular Solids
- 10.7 Ionic Solids
- 10.8 Vapor Pressure and Changes of State
- 10.9 Phase Diagrams
- 11 Properties of Solutions
- 11.1 Solution Composition
- 11.2 The Energies of Solution Formation
- 11.3 Factors Affecting Solubility
- 11.4 The Vapor Pressures of Solutions
- 11.5 Boiling-Point Elevation and Freezing-Point Depression
- 11.6 Osmotic Pressure
- 11.7 Colligative Properties of Electrolyte Solutions
- 11.8 Colloids
- 12 Chemical Kinetics
- 12.1 Reaction Rates
- 12.2 Rate Laws: An Introduction
- 12.3 Determining the Form of the Rate Law
- 12.4 The Integrated Rate Law
- 12.5 Rate Laws: A Summary
- 12.6 Reaction Mechanisms
- 12.7 A Model for Chemical Kinetics
- 12.8 Catalysis
- 13 Chemical Equilibrium
- 13.1 The Equilibrium Condition
- 13.2 The Equilibrium Constant
- 13.3 Equilibrium Expressions Involving Pressures
- 13.4 Heterogeneous Equilibria
- 13.5 Applications of the Equilibrium Constant
- 13.6 Solving Equilibrium Problems
- 13.7 Le Chacirc;telier's Principle
- 14 Acids and Bases
- 14.1 The Nature of Acids and Bases
- 14.2 Acid Strength
- 14.3 The pH Scale
- 14.4 Calculating the pH of Strong Acid Solutions
- 14.5 Calculating the pH of Weak Acid Solutions
- 14.6 Bases
- 14.7 Polyprotic Acids
- 14.8 Acid-Base Properties of Salts
- 14.9 The Effect of Structure on Acid-Base Properties
- 14.10 Acid-Base Properties of Oxides
- 14.11 The Lewis Acid-Base Model
- 14.12 Strategy for Solving Acid-Base Problems: A Summary
- 15 Applications of Aqueous Equilibria Acid-Base Equilibria
- 15.1 Solutions of Acids or Bases Containing a Common Ion
- 15.2 Buffered Solutions
- 15.3 Buffer Capacity
- 15.4 Titrations and pH Curves
- 15.5 Acid-Base Indicators Solubility Equilibria
- 15.6 Solubility Equilibria and the Solubility Product
- 15.7 Precipitation and Qualitative Analysis Complex Ion Equilibria
- 15.8 Equilibria Involving Complex Ions
- 16 Spontaneity, Entropy, and Free Energy
- 16.1 Spontaneous Processes and Entropy
- 16.2 Entropy and the Second Law of Thermodynamics
- 16.3 The Effect of Temperature on Spontaneity
- 16.4 Free Energy
- 16.5 Entropy Changes in Chemical Reactions
- 16.6 Free Energy and Chemical Reactions
- 16.7 The Dependence of Free Energy on Pressure
- 16.8 Free Energy and Equilibrium
- 16.9 Free Energy and Work
- 17 Electrochemistry
- 17.1 Galvanic Cells
- 17.2 Standard Reduction Potential
- 17.3 Cell Potential, Electrical Work, and Free Energy
- 17.4 Dependence of Cell Potential on Concentration
- 17.5 Batteries
- 17.6 Corrosion
- 17.7 Electrolysis
- 17.8 Commercial Electrolytic Processes
- 18 The Nucleus: A Chemist's View
- 18.1 Nuclear Stability and Radioactive Decay
- 18.2 The Kinetics of Radioactive Decay
- 18.3 Nuclear Transformations
- 18.4 Detection and Uses of Radioactivity
- 18.5 Thermodynamic Stability of the Nucleus
- 18.6 Nuclear Fission and Nuclear Fusion
- 18.7 Effects of Radiation
- 19 The Representative Elements: Groups 1A Through 4A
- 19.1 A Survey of the Representative Elements
- 19.2 The Group 1A Elements
- 19.3 Hydrogen
- 19.4 The Group 2A Elements
- 19.5 The Group 3A Elements
- 19.6 The Group 4A Elements
- 20 The Representative Elements: Groups 5A Through 8A
- 20.1 The Group 5A Elements
- 20.2 The Chemistry of Nitrogen
- 20.3 The Chemistry of Phosphorus
- 20.4 The Group 6A Elements
- 20.5 The Chemistry of Oxygen
- 20.6 The Chemistry of Sulfur
- 20.7 The Group 7A Elements
- 20.8 The Group 8A Elements
- 21 Transition Metals and Coordination Chemistry
- 21.1 The Transition Metals: A Survey
- 21.2 The First-Row Transition Metals
- 21.3 Coordination Compounds
- 21.4 Isomerism
- 21.5 Bonding in Complex Ions: The Localized Electron Model
- 21.6 The Crystal Field Model
- 21.7 The Biologic Importance of Coordination Complexes
- 21.8 Metallurgy and Iron and Steel Production
- 22 Organic and Biological Molecules
- 22.1 Alkanes: Saturated Hydrocarbons
- 22.2 Alkenes and Alkynes
- 22.3 Aromatic Hydrocarbons
- 22.4 Hydrocarbon Derivatives
- 22.5 Polymers
- 22.6 Natural Polymers
- Appendix 1